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Citation: Liu Qi-Wang, Cheng Qing-Min, Liu Shu-Tang, Hu Xiang, Huang Xiao-Ying. Sytheses and Structures of Co₃S(CO)₇-clusters Containing a Bridging Bidentate Ligand[J]. Acta Physico-Chimica Sinica, ;1998, 14(03): 283-287. doi: 10.3866/PKU.WHXB19980319 shu

Sytheses and Structures of Co₃S(CO)₇-clusters Containing a Bridging Bidentate Ligand

1.
State Key Laboratory of Structural Chemistry

Available Online: 15 March 1998

By the reaction of Co2(CO)8 with 2-thiohydantoins S-CNHC(O)C(R1) (R2)NC(O)R3(HL), a new cluster with formula Co3(CO)7 (μ3-S) (μ3, η2-S CNC(O)C(CH3)2N C(O)CH3 has been prepared.
The cluster has been characterized by elemental analysis, IR, 1H NMR and MS spectroscopy. The crystal structure of the cluster has been determined by X-ray single crystal diffraction method. The crystal of the cluster is triclinic, belonging to space group P1 and the cell parameters are as follows: a=8.456 (3), b=11.534(3), c= l1.990(4)A, α=107.36(3), β=108.44(5), γ=90.,18(3)°. The structural analysis shows that this molecule contains a tetrahedral cluster framework Co3S and2-thiohydantoin as bridging ligands links up with two cobalt atoms of the framework by S- and N-atom thus -a five member ring of Co2 NCS has been formed.
- Thiohydantoin,
- Tricobalt carbonyl cluster,
- Syntheses and structure
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Sytheses and Structures of Co3S(CO)7-clusters Containing a Bridging Bidentate Ligand

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通讯作者: 陈斌, bchen63@163.com

Sytheses and Structures of Co₃S(CO)₇-clusters Containing a Bridging Bidentate Ligand