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Citation: Ouyang Jian-Ming, Tai Zi-Hou, Tang Wen-Xia. XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions[J]. Acta Physico-Chimica Sinica, ;1998, 14(01): 84-87. doi: 10.3866/PKU.WHXB19980116 shu

XPS Study of LB Films of Amphiphilic Ligand on Surface of the Subphase Containing Metal Ions

1.
Department of Chemistry,Jinan University,Guangzhou 510632

Received Date: 11 March 1997
Available Online: 15 January 1998

The complex formation of 2-hexadecylcarbamoyl-8-hydroxyquinoline(HHQ) monolayers at the air/water interface by reaction with metal ions from the subphase was investigated using X-ray photoelectron spectroscopy. The formation of HHQ-metal complexes leads to the appearance of new peaks assigned to the metal ions. The information on stoichimoetry provided by XPS indicated that a metal ion is coordinated by two HHQ molecules for La3+ and Cd2+ ions, but by one HHQ molecule for Mn2+ and Ni2+ ions.
- X-ray photoelectron spectroscopy,
- Langmuir-Blodgett(LB) Films,
- Metal ion,
- Interface,
- 2-hexadecylcarbamoyl-8-hydroxyquinoline
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