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Citation: Wang Gui-Chang, Sun Yu-Han, Zhong Bing. Calculation of the Electronegativity of Solid Metal Atom and its Application(I)[J]. Acta Physico-Chimica Sinica, ;1998, 14(01): 8-12. doi: 10.3866/PKU.WHXB19980103 shu

Calculation of the Electronegativity of Solid Metal Atom and its Application(I)

1.
State Key Laboratory of Coal Conversion,Institute of Coal Chemistry,Academia Sinica,Taiyuan 030001

Received Date: 3 March 1997
Available Online: 15 January 1998

An empirical method is presented for calculating electronegativity of solid metal atom(Z),that is
X=Pexp(-KsR)
where P is Pauling's element electronegativity,1/Ks is the Thomas-Fermi screening lenthg, R is the radius of univalent metal ions. It is found that the X values can give better relationships between X and some thermochemical properties in catalytic process (such as work function, heat of adsorption, etc.)than Pauling's electronegativity.
- Electronegativity,
- Solid metal atom,
- Work function,
- Heat of adsorption,
- Screen length
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