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Citation: Sun Da-Yong, Liu Zi-Yang, Xu Wen-Guo, Guo Xing-Hua, Liu Shu-Ying. Gas Phase Addition of Rare-earth Fullerenes with Benzene[J]. Acta Physico-Chimica Sinica, ;1997, 13(10): 929-932. doi: 10.3866/PKU.WHXB19971013 shu

Gas Phase Addition of Rare-earth Fullerenes with Benzene

1.
Changchun Institute of Applied Chemistry,Academia Sinica,Changchun 130022

Received Date: 21 January 1997
Available Online: 15 October 1997

Gas phase adduct of endohedral rare-earth fullerenes Nd@C82 with the ion system of benzene- [Nd @ C82-C6H6] + was observed for the first time by ion-molecular reaction under chemical ionization condition. The possible reaction passageway and molecular structures of this gas phase adduct were discussed and a parallel “reversed umbrella” π-π interaction complex of the [C6H6]+ ion reacting with the neutral rare-earth fullerenes Nd@C82 was considered to be much reasonable. The experimental result indicated that endohedral rare-earth fullerenes has relatively active relativity and aromatic properties similar towards benzene molecular ion in gas phase.
- Rare-earth fullerenes,
- Benzene,
- Gas phase ion-molecular reaction
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