Citation:
Luo Ren-Sheng, Yan Jiang-Li, Mao Xi-An. Study of Ligand Exchange Kinetics for Sn(IV) Complex Using 2D NMR[J]. Acta Physico-Chimica Sinica,
;1997, 13(10): 925-928.
doi:
10.3866/PKU.WHXB19971012
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Two-dimensional 1H exchange spectroscopy was applied to study of the ligand exchange kinetics of the complex [Sn2(μ-OH)2Cl6(DMF)2]•4DMF in DMF-d7 solution. The exchange rate constants for the ligand H2O and DMF between free and coordination states were evaluated.
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Keywords:
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Sn(IV) complex
, - 2D EXSY,
- Exchange rate constants
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