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Citation: Zhang Jin, Zhao Jiang, Zhang Hao-Li, Liu Zhong-Fan, Li Hu-Lin. Influence of End Alkyl Chain Length on the Structure of Self-assembled Monolayer of Azobenzene on ld[J]. Acta Physico-Chimica Sinica, ;1997, 13(10): 868-872. doi: 10.3866/PKU.WHXB19971002 shu

Influence of End Alkyl Chain Length on the Structure of Self-assembled Monolayer of Azobenzene on ld

1.
Department of Chemistry,Lanzhou University,Lanzhou 730000;Centre for Intelligent Materials Research(CIMR),College of Chemistry and Molecular Engineering,Peking University,Beijing 100871

Received Date: 27 May 1997
Available Online: 15 October 1997

The end-group dominated molecular orientation in the azobenzene self-assembled monolayers (SAMs), CnAzoC2SH (n=1-4), on ld was evaluated for the first time by grazing incidence reflection absorption FTIR spectroscopy (RA-FTIR). All these azobenzene SAMs have highly-organized and closely-parked structures, with the molecule tilting away gradually from surface normal direction with the increase of end group alkyl length.
- Azobenzene derivatives,
- Self-assembed monolayers,
- Reflection absorption FTIR spectroscopy,
- Molecular orientation
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