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Citation: Zhao Guo-Xi, Yang Zhen-Le, Zhu Bu-Yao. Study on Surface Chemical Properties of Mixed Systems of Derivatives of 10-undecenoic Acid[J]. Acta Physico-Chimica Sinica, ;1997, 13(09): 773-779. doi: 10.3866/PKU.WHXB19970902 shu

Study on Surface Chemical Properties of Mixed Systems of Derivatives of 10-undecenoic Acid

1.
Institute of Physical Chemistry,Peking University,Beijing 100871

Received Date: 26 November 1996
Available Online: 15 September 1997

The surface adsorption and micelle formation of the mi xed systems of trimethyl[2-(10-undecenoyloxyl ethyl)]ammonium iodide and sodium 10-undecenoate have been investigated by tensiometry; The vesicle formation has been also demonstrated by TEM. It has shown that the mixed cationic-anionic surfactants containing the double bond in the end of hydrocarbon chains, as well as those containing saturated hydrocarbon chains, have a high surface activity and a high tendency to adsorb at the air/water surface and to form micelles in the solution; Moreover, quite stable vesicles from these systems can be also formed in the aqueous solution and ethanol/water solution. All of these may be attributed to the strongly electrostatic interaction between the cationic and anionic surfactants.
- 10-undecenoic acid derivatives,
- Cationic-anionic surfactants,
- Surface adsorption,
- Micelle,
- Vesicle
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