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Citation: Li Jing-Hong, Cheng Guang-Jin, Dong Shao-Jun. Electrochemical Study of the Self-exchange between Viologen-thiol Self-assembled Monolayers and Alkanethiol on ld Electrodes[J]. Acta Physico-Chimica Sinica, ;1997, 13(07): 655-658. doi: 10.3866/PKU.WHXB19970717 shu

Electrochemical Study of the Self-exchange between Viologen-thiol Self-assembled Monolayers and Alkanethiol on ld Electrodes

1.
Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Academia Sinica,Changchun 130022

Received Date: 19 November 1996
Available Online: 15 July 1997

The preparation and cyclic voltammetric behaviors of self assembled monolayers (SAMs) containing electroactive viologen group have been investigated. Treatment of this viologen SAM with solutions of alkanethiols results in replacing the electroactive thiol, shifting negatively its formal potentials and decreasing its heterogeneous electron transfer constants along with the immersion time. The aim of the work is to understand the exchange regularity of the mired SAMs on ld electrode surface.
- Self-assembled monolayers,
- Viologen SAMs,
- Self-exchange,
- Electrochemsity
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