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Citation: Wang Chu-Ji, Xiao Ying-Sheng, Ran Qin, Chu Yi-Wei, Chen Cong-Xiang, Yu Shu-Qin, Ma Xing-Xiao. Determination of A-State Streching Frequencies of CF₂ Radical[J]. Acta Physico-Chimica Sinica, ;1997, 13(04): 297-300. doi: 10.3866/PKU.WHXB19970403 shu

Determination of A-State Streching Frequencies of CF₂ Radical

1.
Department of Chemical Physics,University of Science and Technology of China,Hefei 230026

Received Date: 3 December 1996
Available Online: 15 April 1997

Laser induced fluorescence excitation spectroscopy has been used to determine the previously ambiguous assignments of A-state stretching frequencies of CF2 radical under supersonic free jet conditions. The measured frequencies are v’1=1012.1±0.5cm-1, v’3=1180.2±0.5cm-1, which is in od agreement with Cameron's[6] calculation result. Furthermore, some transitions attributed to the (1,n-2,0)←(0,0,0), n≦6 progressions are first reported, and new parameters are derived from the spectra obtained.
- CF₂ radical,
- Stretching frequencies
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Determination of A-State Streching Frequencies of CF2 Radical

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通讯作者: 陈斌, bchen63@163.com

Determination of A-State Streching Frequencies of CF₂ Radical