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Citation: Yao Song-Nian, Wang Chun-Lin, Zhang Cao-Mo, Xiong Hai-Tao, Miao Wei. Influence of the Structure of the Ordered System(PC-H₂O) on the Crystal Structure of CaCO₃[J]. Acta Physico-Chimica Sinica, ;1997, 13(03): 270-273. doi: 10.3866/PKU.WHXB19970316 shu

Influence of the Structure of the Ordered System(PC-H₂O) on the Crystal Structure of CaCO₃

1.
Department of analysis and measurement science,Wuhan University,Wuhan 430072

Received Date: 15 July 1996
Available Online: 15 March 1997

Influence of the concentration of phosphatidylcholine (PC) in the solution of 0.5mol?L-1 CaCl2 on the crystal structure of CaCO3 has been studied by means of X-ray diffraction method. When the concentration of PC is below its CMC, the calcite CaCO3 is formed. It advantageous that CaCl2 reacts with Na2CO3 so as to form vaterite CaCO3 in the lipesome composed of PC more than in the water. The arnount of vaterite CaCO3 formed is increased with increase of concentration of PC. But if the concentration of PC is so increased as to form liquid crystal, then the amount of vaterite decreases obviously. The reason for the difference of crystal type formed has been discussed in the paper.
- Vaterite CaCO₃,
- Bioliquid crystal,
- Structure of lecithin bilayers
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Influence of the Structure of the Ordered System(PC-H2O) on the Crystal Structure of CaCO3

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通讯作者: 陈斌, bchen63@163.com

Influence of the Structure of the Ordered System(PC-H₂O) on the Crystal Structure of CaCO₃