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Citation: Chen Xue-An, Zhao Ling, Li Yan, Chen Ben-Ming. Preparation and Crystal Structure of PbCuP₂O₇[J]. Acta Physico-Chimica Sinica, ;1997, 13(02): 113-118. doi: 10.3866/PKU.WHXB19970204 shu

Preparation and Crystal Structure of PbCuP₂O₇

1.
Institute of Chemistry,Academia Sinica,Beijing 100080

Received Date: 12 April 1996
Available Online: 15 February 1997

Single crystal of PbCuP2O7 has been prepared by the conventional solid state reaction method. Its crystal structure has been determined from X-ray four-circle diffractometer data: P21/n, a=5.381(1), b=8.205(2), c=12.570(3)?, β＝90.49(3)°,Z=4, R=0.054 for 1311 structure factors and 101 variable parameters. The frame-work of PbCuP2O7 consists of corner-sharing CuO5 square pyramids and P2O7 groups forming large tunnels running along α-axis. Pb atoms are located in the penta nal shaped windows, which are formed by the edges of two square pyramid and three PO4 tetrahedra.
- Crystal structure,
- PbCuP₂O₇,
- Single crystal
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Preparation and Crystal Structure of PbCuP2O7

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Preparation and Crystal Structure of PbCuP₂O₇