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Citation: Liu Jun-Fu, Yang Kong-Zhang, Lu Zu-Hong, Ding De-Sheng, Wu Hai-Ming. Studies on Ordered Composite Nanowire Arrays of Tl₂O₃/ Poly-Nvinylcarbazole[J]. Acta Physico-Chimica Sinica, ;1996, 12(10): 865-869. doi: 10.3866/PKU.WHXB19961001 shu

Studies on Ordered Composite Nanowire Arrays of Tl₂O₃/ Poly-Nvinylcarbazole

1.
Institute of Colloid and Interface Chemistry,Shandong University,Jinan 250100

Received Date: 24 May 1996
Available Online: 15 October 1996

Stable monolayers of electropolymerized poly-N-vinylcarbazole (EPVK) and arachidic acid(AA) are obtained on a subphase of alkaline Tl2O3 colloidal solutions. As revealed by the atomic force microscope, there is phase separation in the mixed LB monolayers. Transmission electron microscopic observations reveal that ordered arrays of composite Tl2O3/Epvk nanowires are formed in the mixed monolayers. Formation of the composite nanowire arrays is attributed to the ordered adsorption of Tl2O3 colloidal particles along the polycationic EPVK chains. The composite nanowire array is 3.2nm wide with a spacing of 2.7nm.The composite nanowire arrays can also be formed when pure EPVK is used. Composite LB multilayers of Tl2O3/EPVK nanowire arrays are prepared. The bilayer spacing is 5.54nm.The present study is of importance to the fabrication of inorganic semiconductor/functional polymer composite nanowires.
- Nanowire,
- Thallic oxide,
- Poly-N-vinylcarbazole,
- LB film
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Studies on Ordered Composite Nanowire Arrays of Tl₂O₃/ Poly-Nvinylcarbazole