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Citation: Miao Ming-Ming, Sun Xian-Ru, Shi Jing-Min, Cheng Peng, Laio Dai-Zheng, Jiang Zong-Hui, Wang Geng-Lin. Study on Tetraiodoterephthalato-bidged Cobalt(II) Binuclear Complexes[J]. Acta Physico-Chimica Sinica, ;1996, 12(07): 577-580. doi: 10.3866/PKU.WHXB19960701 shu

Study on Tetraiodoterephthalato-bidged Cobalt(II) Binuclear Complexes

1.
Department of Chemistry,Nankai University,Tianjin 300071

Received Date: 30 June 1995
Available Online: 15 July 1996

Four novel Cobalt(Ⅱ) complexes have been synthesized and characterized, namely [Co2(4I-TPHA)(L) 4 (ClO4)2 (L denotes 1, 10-phenanthroline(phen)(1), 5-nitro1, 10-phenanthroline(NO2-phen)(2), 2,2'- bipyridyl(bpy) (3) and 4. 4'-dimethyl-2, 2'bipyridyl (Me2bpy) (4). respectively),where 4I- TPHA is the tetraiodoterephthalate dianion. The magnetic studies indicate that a weak antiferromagnetic spin exchange imteraction exists between the metal ions.
- Binuclear compexes cobalt(II)-Cobalt(II),
- Tetraiodoterephthalate dianion,
- Antiferromagnetic interaction
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