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Citation: Guo Jun, Jiao Qing-Ze, Lv Hui-Juan, Jiang Da-Zhen, Yang Guang-Hui, Min En-Ze. Synthesis and Adsorption Properties of some Polyoxometalate Pillared Hydrotalcites[J]. Acta Physico-Chimica Sinica, ;1996, 12(06): 573-576. doi: 10.3866/PKU.WHXB19960620 shu

Synthesis and Adsorption Properties of some Polyoxometalate Pillared Hydrotalcites

1.
Department of Chemistry,Jilin University,Changchun 130023

Received Date: 23 October 1995
Available Online: 15 June 1996

Mg-Al hydrotalcites with different Mg/Al ratios and their polyoxometalate intercalates were synthesized by direct ion-exchange reactions. The porous structures of the pillared products were studied by adsorbing various molecules with different, kinetic diameter on them. The results show that the porous structures of the pillared products can be adjusted either by changing the layer charge densities or by changing the pillar densities, i. e. the pore diameter will increase with the increament of the Mg atoms in the layers and the polyoxometalate charges in the gallery.
- Mg/Al atomic ratio,
- Polyoxometalates,
- Pillared hydrotalcites,
- Synthesis,
- Adsorption properties
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