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Citation: Li Yong-Hong, Hong San-Guo. Quantum Chemical Study on the Rearrangements of SCRCR'CO[J]. Acta Physico-Chimica Sinica, ;1996, 12(02): 119-123. doi: 10.3866/PKU.WHXB19960206 shu

Quantum Chemical Study on the Rearrangements of SCRCR'CO

1.
Department of Chemistry,Jiangxi Normal University,Nanchang 330027

Received Date: 8 April 1995
Available Online: 15 February 1996

MINDO/3 MO method has been used to study on the rearrangements of SCRCR′CO. The results obtained show that the rearrangement reaction has lower activation energy when R is an election rich migrating group, and phenyl group can decrease the activation energy of this reaction.
- Rearrangement reaction,
- Transition state,
- Reaction pathway
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