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Citation: Gao Qing-Yu, Wang Yue-Min, Zang Ya-Ru, Ma Ke-qin, Zhao Xue-Zhuang. Nonlinear Phenomena in Uncatalyzed Reaction of Some Sulfur Compounds with H₂O₂[J]. Acta Physico-Chimica Sinica, ;1996, 12(01): 1-3. doi: 10.3866/PKU.WHXB19960101 shu

Nonlinear Phenomena in Uncatalyzed Reaction of Some Sulfur Compounds with H₂O₂

1.
Chemistry Department,Nankai University,Tianjin 300071

Received Date: 18 September 1995
Available Online: 15 January 1996

In absence of catalysts, Oscillations in the oxidation of KSCN、Na2S2O3 and SC(NH2)2 by H2O2 are observed in CSTR experiments, single-peak and other phenomena are observed in batch experiments. Oscillations in pH and Pt potential are antiphase in H2O2-Na2S2O3-H+ system and H2O2-KSCN-OH- system, but oscillations in pH and Pt potential are synchronous in H2O2-SC(NH2)2-H+ system.
- Batch Reactor,
- CSTR,
- Chemical oscillation,
- Nonlinearity,
- Sulfur compounds
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Nonlinear Phenomena in Uncatalyzed Reaction of Some Sulfur Compounds with H2O2

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通讯作者: 陈斌, bchen63@163.com

Nonlinear Phenomena in Uncatalyzed Reaction of Some Sulfur Compounds with H₂O₂