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Citation: Liu Zi-Yang, Hao Guo-Lun, Wang Hua-Yun, Xu Wen-Guo, Guo Xing-Hua, Ma Ge, Ma Deng-Liang, Liu Shu-Ying. Gas-phase Ion-molecular reactions of C₆₀ and C₇₀ with Acetone and Quantum Chemistry Study[J]. Acta Physico-Chimica Sinica, ;1995, 11(08): 751-754. doi: 10.3866/PKU.WHXB19950817 shu

Gas-phase Ion-molecular reactions of C₆₀ and C₇₀ with Acetone and Quantum Chemistry Study

1.
Changchun Institute of Applied Chemistry,The Chinese Academy Sciences,Changchun 130022

Received Date: 29 August 1994
Available Online: 15 August 1995

Gas-phase ion-molecular reactions of C60 and C70 with the ion system of acetone have been studied in this paper. The ions of protoned and acetylized C60 and C70 were formed by the reactions of C60 and C70 with some ions which existed in the ion system when mass spectrometer worked on chemical ionization conditions. The reactivity of C70 is greater than that of C60. Results of quantum chemical calculation for the adduct ions showed a σ bond between the acyl carbon atom and C60 may be formed. These results will provide some valuable informations on the condense-phase acetylization of C60.
- C₆₀,
- C₇₀,
- Acetone,
- Ion-molecular reaction
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Gas-phase Ion-molecular reactions of C60 and C70 with Acetone and Quantum Chemistry Study

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通讯作者: 陈斌, bchen63@163.com

Gas-phase Ion-molecular reactions of C₆₀ and C₇₀ with Acetone and Quantum Chemistry Study