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Citation: Zhu Xiao-Lei, Zhou Zhi-Hua. Investigation on Dipole-dipole Interaction(I)[J]. Acta Physico-Chimica Sinica, ;1995, 11(05): 438-441. doi: 10.3866/PKU.WHXB19950511 shu

Investigation on Dipole-dipole Interaction(I)

1.
Department of Chemistry,Nanjing Normal University,Nanjing 210024

Received Date: 31 January 1994
Available Online: 15 May 1995

The coherent potential approximation (CPA) is used in the calculation of the vibrational spectra for absorbed 12CN- /13CN- mixtures on ld. The theoretical results are compared with the surface IR-spectra of 12CN-/13CN- mixture absorbed on rough Au-electrod. The results show that in the systems consisting of isotopic mixtures of CN-on Au(100), molecules interact mainly through their dipole fields.
- Dipole-dipole interaction,
- CPA,
- Intensity transfer,
- Frequeney shift
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