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Citation: Chen Rui-Zhi, Zheng Shi-Jun, Cai Xin-Hua, Meng Ling-Peng, Wang Dian-Xun. Gas -phase Studies of Cyano Derivatives of Benzene Series by HeI Ultraviolet Photoelectron Spectroscopy[J]. Acta Physico-Chimica Sinica, ;1995, 11(05): 433-437. doi: 10.3866/PKU.WHXB19950510 shu

Gas -phase Studies of Cyano Derivatives of Benzene Series by HeI Ultraviolet Photoelectron Spectroscopy

1.
Chemistry Department,Hebei Teacher's Colleage,Shijiazhuang 050091

Received Date: 29 January 1994
Available Online: 15 May 1995

Gas-phase HeI ultraviolet photoelectron spectra of m-dicyanobenzene, P-dicyanobenzene and 1,2,4,5-tetracyanobenzene are given in this paper. Photoelectron spectra are assigned using MNDO molecular orbital calculation and correlation analysis for benzene and each cyanobenzene. It may be pointed out that there is some effect of the substituted position and numbers of -CN group on the relative ordering levels, splittings and the levels of the two orbitals splitted by elg(π) of benzene.
- Cyanoderivative of benzene,
- HeI Ultraviolet photoelectronspectra;MNDO
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