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Citation:
Cao Yang, Zhu Zhi-Dong, Zhao Bo. Determination of Second-order Polarizabilities of BMC and MMONS by Solvatochromic Method[J]. Acta Physico-Chimica Sinica,
;1995, 11(04): 356-359.
doi:
10.3866/PKU.WHXB19950414
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Second-order polarizabilities of BMC and MMONS were determined by solvatochromic method. The second-order polarizabilities of BMC and MMONS were also calculated by quantum chemical semiempirical CNDO/S-CI method and perturbation theory and second-order nonlinear optical data respectively. Calculated values are in od agreement with experimental results. The effect of molecular and crystal structure on second-order polarizabilities has also been discussed.
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