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Citation: Wang Han-Ming, Yu Ze-Mu, Wang Er-Kang. Electrochemical Study of the Transfer of Bis-1:11 Molybdosilicate Heteropolyanion with Dysprosium across the Liquid/Liquid Interface[J]. Acta Physico-Chimica Sinica, ;1995, 11(03): 242-246. doi: 10.3866/PKU.WHXB19950311 shu

Electrochemical Study of the Transfer of Bis-1:11 Molybdosilicate Heteropolyanion with Dysprosium across the Liquid/Liquid Interface

1.
Laboratory of Electroanalytical Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022

Received Date: 29 January 1994
Available Online: 15 March 1995

The transfer of bis-1:11 molybdosilicate heteropolyanion with dysprosium across the water/nitrobenzene interface has been investigated by chronopotentiometry with linear current scanning and cyclic voltammetry. The standard transfer potential and Gibbs energy estimated from cyclic voltammetry were 0.102V and -39.5kJ.mol-1, respectively. The kinetic parameters of the transfer were determinated by chronopotentiometry with linear current scanning.
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