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Citation: Zhang Hua-Bei, Liang Guo-Ming, Tian An-Min, Yan Guo-Sen. Study on Bonding Behavior of the element Clusters Li^e_n[J]. Acta Physico-Chimica Sinica, ;1994, 10(04): 360-362. doi: 10.3866/PKU.WHXB19940414 shu

Study on Bonding Behavior of the element Clusters Li^e_n

1.
Department of Chemistry, Sichuan University, Chengdu 610064

Received Date: 16 October 1992
Available Online: 15 April 1994

The Localized molecular orbitals of element clusters Li~e_n(n=1-6, 8; e=+1) have been calculated. The results show besides the two-centre bonds, a variety of many center bonds including closed-form and open-form ealst in Li~e_n. The many-centre bonds and the coordination numer as a character of metallic bonds increase with the increasing of the size of clusters. The influences of the geometric structures and electronic states on the bonding have been discussed.
- Localized molecular orbitals,
- Lien elemental clusters,
- Many-centre bonds
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Study on Bonding Behavior of the element Clusters Li^e_n