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Citation: Huang Rong-Bin, Liu Zhao-Yang, Zhao Jian-Hong, Lin Feng-Chen, Zheng Lan-Sun. Studies of Carbon Cluster Anions with a Heteroatom of IIIA or VA Group[J]. Acta Physico-Chimica Sinica, ;1994, 10(04): 308-311. doi: 10.3866/PKU.WHXB19940405 shu

Studies of Carbon Cluster Anions with a Heteroatom of IIIA or VA Group

1.
Department of Chemistry, Xiamen Univeristy, Xiamen 361005

Received Date: 8 September 1992
Available Online: 15 April 1994

A series of carbon cluster anions with a heteroatom have been generated on a home-made apparatus by laser abalation of appropriate samples. The heteroatom includes boron, aluminum, nitrogen, phosphorus or arsenic which is either a ⅢA or a VA group element. The recorded time-of-flight mass spectra show that stabilities of the cluster anions are affected by the composition of the heteroatom. The ⅢA group heteroatom tends to bind with even sizes of carbon atom and the VA group atom selects odd sizes. The even/odd alternation is attributed to the linear configuration of the cluster anions with the heteroatom at the end of the chain.
- Carbon cluster,
- Linear chain,
- Even/odd alternation
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