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Citation: Ma Jian-Fang, Wei Ge-Cheng, Ni Jia-Zuan. Syntheses and Crystal Structures of the Complexes of rare Earth with Fumaric Acid[J]. Acta Physico-Chimica Sinica, ;1993, 9(06): 752-759. doi: 10.3866/PKU.WHXB19930607 shu

Syntheses and Crystal Structures of the Complexes of rare Earth with Fumaric Acid

1.
Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022

Received Date: 25 May 1992
Available Online: 15 December 1993

Six compounds of M_2F_3·12H_2O (M=Eu, Gd, Tb, Y, Er, Lu; H_2F=Fumaric acid) have been synthesized. The structures of Eu(Ⅲ), Tb(Ⅲ), Y(Ⅲ), Er(Ⅲ) and Lu(Ⅲ) compounds have been determined by single crystal X-ray diffraction method. The complex of Eu(Ⅲ) crystallizes in triclinic space group P(1), and the coordination number of Eu~(3+) is ten. The other four complexes crystallize in monclinic space group P2_(1/c), and the coordination numbers of the metal ions are eight. Each of the complexes shows a three-dimensional net structure.
- Fumaric acid; Complex; Synthesis; Crystal structure
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