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Citation: Liu Jin-Song, Zeng Xian-Cheng, Deng Yu. Deduced Extent Method for Thermokinetics II. Thermokinetic Studies on 2-2 Type Reversible Reaction[J]. Acta Physico-Chimica Sinica, ;1993, 9(05): 698-701. doi: 10.3866/PKU.WHXB19930524 shu

Deduced Extent Method for Thermokinetics II. Thermokinetic Studies on 2-2 Type Reversible Reaction

1.
Department of Chemistry, Sichuan University, Chengdu 610064

Received Date: 11 March 1992
Available Online: 15 October 1993

Thermokinetics for a 2-2 reversible reaction system, 2-nitropropane with mor-pholion, have been studied at 25 and 30 ℃ in 40% (v/v) ethyl alcohol aqueous solution by the reduced extent method.
The rate constants、equilibrium constants、activation energies、activation free-energies、activation ethalpies and activation entropies of the reversible reaction have been calculated.
The concept of the reduced extent of thermokinetics and the experimetal results have been discussed in this paper.
- Thermokinetics; Reduced extent method; Reversible reaction; Calorimetry
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