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Citation: Wang Hai-Qing, Gu Yue-Shu, Guo Jing-Zhong, Liu Chuan-Pu, Yin Yong-Jia, Cao De-Zhao. Quenching Rate Constants for Metastable Molecule CS(α³П)[J]. Acta Physico-Chimica Sinica, ;1993, 9(02): 247-251. doi: 10.3866/PKU.WHXB19930220 shu

Quenching Rate Constants for Metastable Molecule CS(α³П)

1.
Chemistry Department, Shandong University, Jinan 250100; Anhui Institute of Optics and Fine Mechanics, Academia Sinica, Hefei 230031

Received Date: 31 October 1991
Available Online: 15 April 1993

The metastable molecule CS(a~3Π) has been obtained, by the energy transfer reaction of He(2~3S) with CS_2 in a discharge-flow system The technique of fixed observation-point was used to obtained the quenching rate constants of CS(a~3Π) with various reagents CO_2, CS_2, ICl, H_2O, NOCl, CH_2Cl_2, CHF_2Cl and SF_6. Thc mechanism for quenching has been discussed.
- CS(α³П); Reaction of metastable atom; Quenching rate constant
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Quenching Rate Constants for Metastable Molecule CS(α3П)

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Quenching Rate Constants for Metastable Molecule CS(α³П)