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Citation: Zhao Liang-Zhong. Determination of O_1s Binding Energies of the Alkaline Earth Oxides and Peroxide[J]. Acta Physico-Chimica Sinica, ;1993, 9(02): 170-174. doi: 10.3866/PKU.WHXB19930206 shu

Determination of O_1s Binding Energies of the Alkaline Earth Oxides and Peroxide

Zhao Liang-Zhong

1.
Institute of Chemistry, Academia Sinica, Beijing 100080

Received Date: 11 November 1991
Available Online: 15 April 1993

The O_(1s) binding energy of M , CaO, SrO and BaO were determined by means of XPS. Prior to the determination,the samples were heated in the spectrometer at 400 ℃. The surface carbonates were partly decomposed and the O_(1s) spectra of lattice oxygen of the oxides were recorded. The O_(1s) binding energies of M , CaO and SrO determined by present work are lower than that reported in the literatures. A reasonable correlation between O_(1s) binding energies determined by present work and the partial charge on oxygen calculated by Sanderson for these alkaline earth oxides are found. The O_(1s) binding energy of BaO_2 determined by present work is 530.9 eV which is also lower than that reported in the literatures.
- XPS; O_1s binding energy; Alkaline earth oxides; Barium peroxide
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Determination of O1s Binding Energies of the Alkaline Earth Oxides and Peroxide

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Determination of O_1s Binding Energies of the Alkaline Earth Oxides and Peroxide