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Citation: Wang Zeng-Lin, Hu Ning-Hai, Niu Chun-Ji, Ni Jia-Zuan, Cui Ai-Li. Crystal Structure and Thermal Analysis of Erbium Complex with Benzene Acetic Acid[J]. Acta Physico-Chimica Sinica, ;1992, 8(05): 642-646. doi: 10.3866/PKU.WHXB19920513 shu

Crystal Structure and Thermal Analysis of Erbium Complex with Benzene Acetic Acid

1.
Changchun Institute of Chemistry, Chinese Academy of Science, Changchun 130022; Changchun Specialized School of Metallurgy and Geology, Changchun 130021

Received Date: 12 April 1991
Available Online: 15 October 1992

The crystal structure of erbium (Ⅲ) complex of benzene acetic acid is reported. The complex crystallizes in the monoclinic space group P_2_1/a with a=0.9008(3) nm, b=1.4242(5) nm, c=1.8437(7) nm; β=98.80(3)°, V=2.337(1) nm~3, Z=4. The mechanism of thermal decomposition of complex has been studied by TG-DTG-DTA. The activation energy for dehydration reaction has been calculated by Freeman-Carroll method. The enthalpy change for dehydration and phase change process has been determined.
- Erbium eomplex; Crystal structure; Thermal analysis
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