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Citation: Yang Han-Xi, Xiao Yi-Jin, Zhu Ling, Sheng Rong-Sheng, Chen Su-Nian, Li Gui-Hua. The Steady State Properties of Electrochemical Reduction of C₆₀[J]. Acta Physico-Chimica Sinica, ;1992, 8(05): 580-582. doi: 10.3866/PKU.WHXB19920502 shu

The Steady State Properties of Electrochemical Reduction of C₆₀

1.
Department of Chemistry, Wuhan University, Wuhan 430072; Analytical Centre, Wuhan University, Wuhan 430072

Received Date: 9 May 1992
Available Online: 15 October 1992

The electroreduction of C_(60) was investigated by microelectrode voltammetry and in-situ optically transparent thin layer electrode technique(OTTLE). From the mea-surements of steady-state polarization curves and the absorbance dependence of C_(60) on reduction potentials, it is found that the electroreduction of C_(60) occurs in a succes-sive three step one-electron reduction. The diffusion coefficient and standard equilib-rium potential were evaluated to be 5.3×10~(-6)cm~2·s~(-1) and -0.40±0.02 V(vs. Ag/AgCl) respectively.
- C₆₀; Electroreduction; Standard equilibrium potential; UV/Vis spectroscopy
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The Steady State Properties of Electrochemical Reduction of C60

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The Steady State Properties of Electrochemical Reduction of C₆₀