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Citation: Yu Xiu-Fen, Wang Zhe-Min. OXO-Centered Heterotrinuclear Transition Metal Carboxylate Complexes Studies on the Electronic Spectra of[Fe₂MO(CH₃COO)₆Py₃].Py and [Fe₂MO(CCl₃COO)₃(THF)3](M=Mn,Co,Ni)[J]. Acta Physico-Chimica Sinica, ;1991, 7(05): 577-581. doi: 10.3866/PKU.WHXB19910512 shu

OXO-Centered Heterotrinuclear Transition Metal Carboxylate Complexes Studies on the Electronic Spectra of[Fe₂MO(CH₃COO)₆Py₃].Py and [Fe₂MO(CCl₃COO)₃(THF)3](M=Mn,Co,Ni)

Yu Xiu-Fen ,
Wang Zhe-Min

1.

Fuzhou Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Academia Sinica; Department of Chemistry, Fuzhou Universtry, Fuzhou 350002

Received Date: 10 April 1990
Available Online: 15 October 1991

The UV/VIS spectra for pyridine solution of complexes [Fe_2MO(CH_3COO)_6Py_2]·Py and THF solution of complexes Fe_2MO(CCl_3COO)_6(THF)_3 were studied. The d-d transitions were assigned and the ligand field parameters(B,D_q,β) were calculated for the related metal ions according to ligand field theory (Tanabe-Sugano diagram) in terms of O_h symmetry and reasonably od fits were obtained for the calculated and observed frequencies. The calculated results show that (1) the larger the ionic potential for M~(2+) ion, the larger the values of B, D_q for Fe~(3+) ion (2) the ligand field parameters of metal ions vary in parallel with the electronagativity of R in RCOO~-.
- Electronic spectra; Cluster; Carboxylate complex
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OXO-Centered Heterotrinuclear Transition Metal Carboxylate Complexes Studies on the Electronic Spectra of[Fe2MO(CH3COO)6Py3].Py and [Fe2MO(CCl3COO)3(THF)3](M=Mn,Co,Ni)

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通讯作者: 陈斌, bchen63@163.com

OXO-Centered Heterotrinuclear Transition Metal Carboxylate Complexes Studies on the Electronic Spectra of[Fe₂MO(CH₃COO)₆Py₃].Py and [Fe₂MO(CCl₃COO)₃(THF)3](M=Mn,Co,Ni)