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Citation: Zhu Zhi-Ang, Xia Xin, Chen Rong-Ti. Kinetics of the Formation of (Para-Substituted Tetraphenylporphinato)-Copper(II) and the Catalytic Effect of Other Matal Ions[J]. Acta Physico-Chimica Sinica, ;1991, 7(04): 456-461. doi: 10.3866/PKU.WHXB19910415 shu

Kinetics of the Formation of (Para-Substituted Tetraphenylporphinato)-Copper(II) and the Catalytic Effect of Other Matal Ions

1.
Department of Chemistry, Nankai University, Tianjin 300071

Received Date: 10 March 1990
Available Online: 15 August 1991

The kinetics of formation reaction of Copper(Ⅱ) with para-substituted tetraphenylporphyrin H_2(p-X)TPP (X=NO_2,Cl,H, CH_3,OCH_3) in dimethyl sulfoxide solution and the catalytic effect of Cadmium(Ⅱ) ion have been studied on Shimadru UV-240 spectrophotometer. The mechanisms were proposed and the effect of Hg(Ⅱ), Pb(Ⅱ) on this reaction was investigated. od LFER (linear free energy relationahips) between reaction rate constant/equilibrium constant with the Hammett subtituent constant σ have been ob served in certain cases.
- (Para-substituted tetraphenylporphinato)-Copper(II); Kinetics of formation Mechanisms
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