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Citation: ng Hui-Hao, Wang Shou-Xiang, Xu Hai-Han. Study on the Briggs-Rauscher Type Oscillatary System Using Diacetone Alcohol as Organic Compound and Cerium (III) as Catalyst[J]. Acta Physico-Chimica Sinica, ;1991, 7(02): 184-190. doi: 10.3866/PKU.WHXB19910211 shu

Study on the Briggs-Rauscher Type Oscillatary System Using Diacetone Alcohol as Organic Compound and Cerium (III) as Catalyst

1.
Institute of Shanghai Chemical Technology, Shanghai 200233; Chemistry Department, Shanghai Normal University

Received Date: 10 July 1989
Available Online: 15 April 1991

The oscillatary behavior of diacetone alcohol(DA)-KIO_3-H_2O_2-H_2SO_4-Ce~(3+) system has been studied.The system may oscillate in the concentration ranges of H_2SO_4 0.11—0.24, KIO_3 0.019—0.048; Ce~(3+) 5.95×10~(-4)—3.57×10~(-3), DA 0.4—3.22 and H_2O_2 0.40—1.99 mol·dm~(-3) respectively.
Using Hg_2SO_4 electrode as the reference electrode, the potential of I~- and the redox potential show oscillatary wave behavior in XWT balance recorder.
According to our expreimental results, We may said seen that ...
- Diacetone alcohol; Cerium(III); Oscillatary system; Catalyst
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