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Citation: Xin Min, Sun Xiao-Lin, Liu Qi-Wang, Hu Yu-Cai. The Crystal and Molecular Structure of β-Cyanoethyl-α-Ferrocenylhalogenbenzyl Ethers[J]. Acta Physico-Chimica Sinica, ;1991, 7(02): 136-139. doi: 10.3866/PKU.WHXB19910202 shu

The Crystal and Molecular Structure of β-Cyanoethyl-α-Ferrocenylhalogenbenzyl Ethers

1.
Department of Chemistry, Neimenggu University, Huhehaote 010021

Received Date: 17 November 1989
Available Online: 15 April 1991

We have reported the structure of β-cyanoethyf-a-ferrocenylfluorobenzyl ether. Present study is concerned with the crystal and molecular structures of serious β-cyanoethyl-α-ferrocenylhalogenbenzyl ethers (C_5H_5FeC_5H_4CH (OCH_2CH_2CN)C_6H_4X) (X = F, Cl, Br, I). All crystals were solved with direct method and fourier synthesis. The differences of the structures caused by the different halogen atoms are discussed.
The results have shown there are two types of molecular configuration. A for X=F and B for X=Cl, Br, I.
- Crystal structure; β-Cyanoethyl-α-ferrocenylhalogenbenzyl ethers
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