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Citation: Yang Qing-Chuan, Li Yi-Li, Tang You-Qi, Fu Heng. Study on the Thermal Motion N-Phenylphthalimide and 2-Phenylquinoxaline in Solid State[J]. Acta Physico-Chimica Sinica, ;1991, 7(01): 77-81. doi: 10.3866/PKU.WHXB19910112 shu

Study on the Thermal Motion N-Phenylphthalimide and 2-Phenylquinoxaline in Solid State

1.
Institute of Physical Chemistry, Peking University; Institute of Chemistry, Academia Sinica

Received Date: 21 September 1989
Available Online: 15 February 1991

On the basis of the data of single crystal structure analysis, the thermal motion analysis for the crystal molecules of N-phenylphthalimide (Ⅰ) and 2-phenylquinoxaline (Ⅱ) was carried out. It is shown that in solid state the molecule of compound I behaves dynamicaly as a rigid molecule and an intramolecular vibration of the substitued pheny group with <ω~2>=53(25) deg·~2 around C(8)—C(9) should be included in the molecular thermal motion of compound Ⅱ .
- N-phenylphthalimide; 2-Phenylquinoxaline; Crystal Structure; Crystal molecular thermal motion
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