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Citation: Chen Cong-Xiang, Gao Yi-De, Zhu Meng-Xia, Kong Fan-Ao, Koda S.. THE KINETIC STUDY OF REACTION O(³P) AND SILANE[J]. Acta Physico-Chimica Sinica, ;1990, 6(06): 660-665. doi: 10.3866/PKU.WHXB19900606 shu

THE KINETIC STUDY OF REACTION O(³P) AND SILANE

1.
Department of Modern Chemistry; University of Science and Technology Department of Reaction Chemistry; Faculty of Engineering; The University of Tokyo; Tokyo; Japan

Received Date: 9 May 1989
Available Online: 15 December 1990

The measurement of rate constant of reaction O~3(P) + SiH_4 with discharge flow-chemiluminescence technique is presented. The Arrhenius form of the rate constant over temperature range 293--413 K is
k=(1.05±0.36)×10~(-10)exp[(-3.06±0.10)kcal·mol~(-1)/RT]cm~3·molecule~(-1)·s~(-1)
Using transition-state theory, the result was extrapolated to temperature range of 200--2000 K. The calculated dependence of the rate constant on temperature with three parameters is
k=7.67×10~(-19)T~(2.59)exp (-720 cal·mol~(-1)/RT)cm~3·molecule~(-1)·s~(-1).
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THE KINETIC STUDY OF REACTION O(³P) AND SILANE