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Citation: Zhou Zhong-Yuan, Yin Zhan-Feng, Zang Yan, Wang Guo-Xiong, Zeng Cheng, Dai An-Bang. Synthesis and Crystal Structure of Nickel (II) Complex with BIS-Schiff Bases From Picoli-naldehyde N-Oxide and 1,2-Propanediamine[J]. Acta Physico-Chimica Sinica, ;1990, 6(05): 556-561. doi: 10.3866/PKU.WHXB19900509 shu

Synthesis and Crystal Structure of Nickel (II) Complex with BIS-Schiff Bases From Picoli-naldehyde N-Oxide and 1,2-Propanediamine

1.
Chengdu Center of Analysis and Determination, Academia Sinica, Chengdu; Coordination Chemistry Institute, Nanjing University, Nanjing

Received Date: 5 July 1989
Available Online: 15 October 1990

A new nickel (II) complex with bis-schiff bases from picolinaldehyde N-oxide and 1,2-propanediamine, [Ni (piopn) (H_2O)_2] (ClO_4)_2 has been synthesised and its crystal structure has been determined. The crystal belongs to monoclinic system, space group C_c, with cell dimensions: a=0.7397(3) nm, b=1.3187(7) nm, c=2.5502(14) nm, β=102.18(4)°, V=224.10 nm, D_c=1.71 g·cm~(-3), F(000)=1135.8, μ=11.65 cm~(-1). According to the semiempirical MO theory calculation, the relationships between IR frequency shifts of ν_(C=N) and ν_(N-O) bands and their characteristics of chemical bonds have been discussed.
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