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Citation: Liu Rui-Lin, Fang Ji-Ye, Ding Hui-Wen, Ni Chao-Shuo, Li Zhi-Fen, Zheng Guo-Kang. Partial Molal Volumes of some Nonpolar and Polar Solutes in Benzene, Methanol and Their Mixtures[J]. Acta Physico-Chimica Sinica, ;1990, 6(04): 485-490. doi: 10.3866/PKU.WHXB19900418 shu

Partial Molal Volumes of some Nonpolar and Polar Solutes in Benzene, Methanol and Their Mixtures

1.
Institute of Physical Chemistry, Peking University; Department of Chemistry, Lanzhou University

Received Date: 24 December 1988
Available Online: 15 August 1990

Partial molal volumes of ethanol, cyclohaxane, trichloromethane, toluene, acetone, carbon tetrachloride, acetonitrile, DMF, and DMSO in methanol, benzene, and their mixtures at infinite dilution at 298.15 K were determined with density measurement. The concentration of solutes for density measurement is in the range from 0.2 to 1.5 mol·kg~(-1) solvent. The compositions of methanol-benzene mixture lay between mole fraction 0 and 1. Variation of solute partial molal volumes with composition of methanol-benzene mixture was attributed to several aspects of molecular interaction, i.e. physical type interaction among three kinds of molecules; hydrogen bond asociation between solute and methanol molecules; and weak complex between solute and methanol or benzene.
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