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Citation: Zhang Shu ng*, Ni Jiazuan, Liang Yingqiu, Zhao Wenyun, Zhang Yunfu, Xu Weiqing. SYNTHESIS AND VIBRATIONAL SPECTRUM STUDIES OF RARE EARTH COMPLEXES WITH CYCLOHEXANE CARBOXYLIC ACID[J]. Acta Physico-Chimica Sinica, ;1989, 5(05): 613-620. doi: 10.3866/PKU.WHXB19890522 shu

SYNTHESIS AND VIBRATIONAL SPECTRUM STUDIES OF RARE EARTH COMPLEXES WITH CYCLOHEXANE CARBOXYLIC ACID

1.
Changchun Institute of Applied Chemistry; Academia Sinia; Theoretical Chemistry Institute; Jilin University

Received Date: 3 January 1988
Available Online: 15 October 1989

The solid state complexes of trivalent lanthanid, yttrium and scandium with cyclohexane carboxylic acid have been isolated and characterized by IR and Raman spectroscopy. It was found that there are only chelated carboxylate groups in the scandium complex and that there are the chelated, bridged and chelate-bridged carboxylate groups in other rare earth complexes. The former is a mononuclear complex and the latter is a polynuclear polymer. The RE—O coordinate bonds possess the characters of convalent ionic bond.
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