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Citation:
Lu Juntao, Liu Xiaoping, Zha Quansin. ESR STUDIES OF CuTAPP SUPPORTED ON ACTIVE CARBON (Ⅱ)[J]. Acta Physico-Chimica Sinica,
;1989, 5(02): 202-205.
doi:
10.3866/PKU.WHXB19890214
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ESR studies were carried out in detail to investigate the changes of CuTAPP (cppper tetra-(p-trimethylanmoniumphyenl) porphine iodide) supported on active carbon during room temperature shelving and heat-treatment.Between room temperature and round 50℃, the resolution of the ESR spectra was found to vary with temperature and relative humidity reversibly. A mechanism of two-dimensional diffusion of the macrocyclic compound in the adsorbed liquid film was suggested to interprate the change in spectral resolution. The ESR spectra after heat-treat-ment at temperatures ranging from 150 to 600 ℃ were also reported and discussed briefly.
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