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Citation: Li Shutao, Han Jingcheng, Liu Houxiang, Li Zhaolin, Wu Cunkai,
Shi Jiliang, Li Fanglin. MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)₅[J]. Acta Physico-Chimica Sinica, ;1988, 4(06): 669-672. doi: 10.3866/PKU.WHXB19880621 shu

MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)₅

1.
Laboratory of Laser Spectroscopy; Anhui Institute of Optics and Fine Mechanics; Academia Sinica
Shanghai Institute of Organic Chemistry; Academia Sinica

Received Date: 26 July 1986
Available Online: 15 December 1988

Multiphoton dissociation-ionization dynamics of Fe(CO)_5 were studied mass spectrometrically with a molecular beam and XeCl excimer laser. The results show that Fe(CO)_n~+ (n= 1,2,… ,5) and Fe_2(CO)_4~+ ions are formed mainly via ion-molecule reaction between Fe~+ and Fe(CO)_5 and dissociation following. A “ladder” model of Fe(CO)_5 photodissociation is presented in the paper.
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MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)5

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MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)₅