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Citation: Han Keli, He Guozhong, Lou Nanquan. THE LASER INDUCED FLUORESCENCE STUDIES OF THE REACTIONS Ca+C₂H_6-nCl_n (n=2,3,4,)[J]. Acta Physico-Chimica Sinica, ;1988, 4(06): 665-668. doi: 10.3866/PKU.WHXB19880620 shu

THE LASER INDUCED FLUORESCENCE STUDIES OF THE REACTIONS Ca+C₂H_6-nCl_n (n=2,3,4,)

1.
Dalian Institute of Chemical Physics; CAS

Received Date: 25 May 1987
Available Online: 15 December 1988

The internal state distributions of nascent CaCl formed in the reactions Ca + (1,1) and (1,2) C_2H_4Cl_2、(1,1,2) C_2H_2Cl_3, (1,1,2,2) C_2H_2Cl_4 have been studied by means of the laser induced fluorescence (LIF) in the beam-gas apparatus. The results showed that the vibrational distributions of the CaCl products from Ca+ (1, 1) C_2H_4Cl_2. (1,1,2,2) C_2H_2Cl_4 are similar to vibrational distributions of the CaCl products from Ca + CH_2Cl_2、CHCl_3, respectively. However, the vibrational distribution of the CaCl product from Ca+(1,1,2) C_2H_3Cl_3 is equivalent to the combination of that from Ca+(1,2) C_2H_4Cl_2 and Ca+(1,1,2,2) C_2H_2Cl_4. No LIF signal has been found in the reaction Ca+(1,1) C_2H_4Cl_2.
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THE LASER INDUCED FLUORESCENCE STUDIES OF THE REACTIONS Ca+C2H6-nCln (n=2,3,4,)

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通讯作者: 陈斌, bchen63@163.com

THE LASER INDUCED FLUORESCENCE STUDIES OF THE REACTIONS Ca+C₂H_6-nCl_n (n=2,3,4,)