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Citation: Xue Rongjian. CONDUCTIVITY AND RELAXATION WITH SOLUTION OF LITHIUM PERCHLORATE IN DIMETHYL SILOXANE-ETHYLENE OXIDE COPOLYMER[J]. Acta Physico-Chimica Sinica, ;1988, 4(06): 636-640. doi: 10.3866/PKU.WHXB19880613 shu

CONDUCTIVITY AND RELAXATION WITH SOLUTION OF LITHIUM PERCHLORATE IN DIMETHYL SILOXANE-ETHYLENE OXIDE COPOLYMER

Xue Rongjian

1.
Institute of Physics; Academia Sinica Beijing; China

Received Date: 16 June 1987
Available Online: 15 December 1988

The conductivity and relaxation of the solutions of LiClO_4 in dimethyl siloxane-ethylene oxide copolymer (named DMS:EO:LiClO_4 for short) have been investigated systematically. The value of optimum of the conductivity is higher than 10~(-4)Scm~(-1) at room temperature at 0.394 mol L~(-1).
From comparison it was pointed that containing siloxane and the salts easy to be disoeiated in copolymer with PEO is helpful for promoting motion of ions.
The peparation and conductivity of the films obtained from the solution only by heat were also mentioned.
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