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Citation: Zhao Bing, Liu Juzheng*, Liang Yingqiu, Tang Aoqing. STUDIES ON VIBRATION SPECTRA AND EHMO FOR CONJUGATION AND UNCONJUGATION UNSATURATED ESTER[J]. Acta Physico-Chimica Sinica, ;1988, 4(06): 617-623. doi: 10.3866/PKU.WHXB19880610 shu

STUDIES ON VIBRATION SPECTRA AND EHMO FOR CONJUGATION AND UNCONJUGATION UNSATURATED ESTER

1.
Institute of Theoretical Chemistry; Jilin University; Chang Chun

Received Date: 9 May 1987
Available Online: 15 December 1988

Tracing out dehydrated reaction of β-hydroxy ester by FT-IR, luster Raman spectroscopy and EHMO calculation,it is found that the distribution for products, α,β-and, β, γ-unsaturated ester is dependent on super-conjugation of substitutedm ethyl on β-carbon. And it has been proved that the reaction examined is akinetic control.
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