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Citation: Huang Jinshun*, Cai Qingrong, He Meiyun, Huang Mingsheng, Lu Jiaxi. SYNTHESIS AND STRUCTURE OF (η⁵-C₅H₅)₄Mo₄Fe₂(μ₃-S)₅(CO)₅[J]. Acta Physico-Chimica Sinica, ;1988, 4(05): 531-534. doi: 10.3866/PKU.WHXB19880518 shu

SYNTHESIS AND STRUCTURE OF (η⁵-C₅H₅)₄Mo₄Fe₂(μ₃-S)₅(CO)₅

1.
Fujian Institute of Research on the Structure of Matter; Academa Sinica

Received Date: 10 February 1987
Available Online: 15 October 1988

(η~5-C_5H_5)_4Mo_4Fe_2(μ_3-S)_5(CO)_5 have been prepared from (η~5-C_5H_5)_2Mo_2(CO)_6 and Fe_8S_2(CO)_9 under toluene reflux for 14.5 hrs.The crystal and molecular structures of (η~5-C_5H_5)_4Mo_4Fe_2(μ_3-S)_5(CO)_5 were studied by X-ray structure analysis. The Crystallographic data are as follows: monoclinic, space group P2_1/n, unit cell: a=1.0589(4), b=1.7260(4), c=1.8963(4) nm, β=101.44(2)°, V=3.3967 nm, D_c=2.06 gcm~(-3) for Z=4, X-ray data were obtained over the range of 2°<2θ<50° via the ω-2θ scan mode with MoKα radiation on an Enraf-Nonius CAD4 diffractometer. The structure was solved by direct method (MULTAN) and refined by full matrix least-squares techniques for 3993 reflections with I>2σ(I), The final R=0.081. Figure 1 illustrates the configuration of the molecule (η~5-C_5H_5)_4Mo_4Fe_2(μ_3-S)_5(CO)_5, composing of a cubane-like (FeMo_3S_4) core and a tri nal pyramid (MoFe_2S) core, which linked by sharing Fe(1) atom.
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SYNTHESIS AND STRUCTURE OF (η5-C5H5)4Mo4Fe2(μ3-S)5(CO)5

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通讯作者: 陈斌, bchen63@163.com

SYNTHESIS AND STRUCTURE OF (η⁵-C₅H₅)₄Mo₄Fe₂(μ₃-S)₅(CO)₅