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Citation: Yuan Wei. STUDY OF DISSOCIATION OF PROPYLENE OXIDE AT A SILVER WIRE[J]. Acta Physico-Chimica Sinica, ;1988, 4(04): 436-440. doi: 10.3866/PKU.WHXB19880423 shu

STUDY OF DISSOCIATION OF PROPYLENE OXIDE AT A SILVER WIRE

Yuan Wei

1.
Department of Applied Chemistry; Beijing Institute of Chemical Technology

Received Date: 9 May 1987
Available Online: 15 August 1988

Propylene oxide catalytically dissociates at the silver wire. The first-step product of this reaction is not acetone, but propyl aldehyde. According to the new assumptions suggested, the reaction probability per encounter has been simulated by
p_m=∫~∞_(E_0) 1/(kT) e~(-E/kT)dE/∫~∞_(E_d) 1/(kT)e~(-E/kT)dE
and a satisfactory result has been achieved in both qualitative and quantitative aspects. The energy transfer efficiency at gas-solid surface and the essence of catalytic action have also been reviewed concisely.
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