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Citation: Cao Jianru*, Wen Ye, Zhang Jianming, Qu Haogang, Zhong Xian, Fang Wanquan, Wu Xiaojun, Zhu Qihe, . THE REACTION CHANNELS AND FRAGMENT ENERGY DISTRIBUTIONS OF THE LASER PHOTOFRAGMENTATION OF C₂H₅I[J]. Acta Physico-Chimica Sinica, ;1988, 4(03): 256-261. doi: 10.3866/PKU.WHXB19880307 shu

THE REACTION CHANNELS AND FRAGMENT ENERGY DISTRIBUTIONS OF THE LASER PHOTOFRAGMENTATION OF C₂H₅I

1.
Institute of Chemistry; Academia Sinica; Beijing

Corresponding author: ,
Received Date: 8 November 1986
Available Online: 15 June 1988

The translational and internal energy distributions of the photofragments for the processes C_2H_5I→C_2H_5+I~*(~2p_(1/2)) and C_2H_5I→C_2H_5+I(~2p_(3/2))have been measured by using a rotatable molecular beam and time of flight method. The ratio I~*/I determined is 2.37. The characteristics of the electronic excited state, the origin of the I(~2p_(3/2)) channel and the vibrational excitations in the ethyl radicals are discussed.
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THE REACTION CHANNELS AND FRAGMENT ENERGY DISTRIBUTIONS OF THE LASER PHOTOFRAGMENTATION OF C₂H₅I