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Citation: Shen Guanlin*, Li Xuechu, Ning Baogang, Lou Nanquan. THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N₂O[J]. Acta Physico-Chimica Sinica, ;1988, 4(01): 77-79. doi: 10.3866/PKU.WHXB19880115 shu

THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N₂O

1.
Dalian Institute of Chemical Physics; Academia Sinica

Received Date: 7 July 1986
Available Online: 15 February 1988

The emission spectra of BiO(A ~2Π_(1/2)) have been first obtained by studying the reaction Bi+N_2O in the heat pipe oven. 18 new bands are obtained from the emission spectra of BiO(A ~2Π_(1/2)) which are attributed to the reaction of atomic Bi~*(~2D_(3/2)) with N_2O(~1Σ_g~+). The metastable Bi~*(~2D_(3/2)) is produced by the following processes: Bi(~4S_(3/2))+N_2O(~1Σ_g~+)→BiO(X_2~2Π_(3/2)), and then,BiO(X_2~2Π_(3/2))+Bi(~4S_(3/2))→Bi~*(~2D_(3/2))+BiO(X_1~2Π_(1/2)).
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THE MECHANISM OF CHEMILUMINESCENT REACTION OF Bi+N₂O