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Citation: Li Guifang, Zhao Yang, Liu Changyan. THE CHARGE-TRANSFER COMPLEXES OF POLY (N-VINYL-CARBAZOLE) AND NITROFLUORENONES IN DIFFERENT SOLVENTS[J]. Acta Physico-Chimica Sinica, ;1987, 3(05): 551-554. doi: 10.3866/PKU.WHXB19870521 shu

THE CHARGE-TRANSFER COMPLEXES OF POLY (N-VINYL-CARBAZOLE) AND NITROFLUORENONES IN DIFFERENT SOLVENTS

1.
Institute of Chemistry; Academia Sinica; Beijing

Received Date: 9 April 1986
Available Online: 15 October 1987

The charge-transfer complexes of poly(N-vinylcarbazole) (Mn=7200) and nitro- fluorenones were studied with VPO in different solvents. The relationship between equilibrium constant and solvent dipole moment was examined. The results obtained from polymer and model compound were compared, and the reason of their difference was explained. The relationship between the equilibrium constant and the molecular weight was given:
InK_(CT)=InK_(CT)~∞+2M_0/M(InK°-InK~∞)
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