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Citation: You Xiaozeng, Wu Weixiong, Li Cun, Li Chongde, Qian Changtao. STUDY OF THE ¹³C NMR CHEMICAL SHIFT ON THE THF-COORDINATED (1,1'-TRIME-THYLENEDICYCLOPENTADIENYL) (TERT-BUTYL) LANTHANIDE COMPLEX[J]. Acta Physico-Chimica Sinica, ;1987, 3(04): 430-434. doi: 10.3866/PKU.WHXB19870418 shu

STUDY OF THE ¹³C NMR CHEMICAL SHIFT ON THE THF-COORDINATED (1,1'-TRIME-THYLENEDICYCLOPENTADIENYL) (TERT-BUTYL) LANTHANIDE COMPLEX

1.
Coordination Chemistry Institute; Nanjing University
Shanghai Institute of Organic Chemistry; Academia Sinica

Received Date: 19 January 1986
Available Online: 15 August 1987

We have synthesized the THF-coordinated(1,1′-Trimethylenedicyclopentadienyl) (tert-butyl) lanthanide complex. The ~(13)C NMR spectrum in tetrahydrofuran-d_8 so- lution has been determined and assigned. A theoritical calculation of ~(13)C NMR che- mical shift based on our INDO/σ program has been applied to this compound as the first calculation for lanthanide complex which included f orbitals. The corela- tion between the theoretical calculation results and the experimental data is sati- sfactory.
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STUDY OF THE 13C NMR CHEMICAL SHIFT ON THE THF-COORDINATED (1,1'-TRIME-THYLENEDICYCLOPENTADIENYL) (TERT-BUTYL) LANTHANIDE COMPLEX

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通讯作者: 陈斌, bchen63@163.com

STUDY OF THE ¹³C NMR CHEMICAL SHIFT ON THE THF-COORDINATED (1,1'-TRIME-THYLENEDICYCLOPENTADIENYL) (TERT-BUTYL) LANTHANIDE COMPLEX