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Citation: Shen Zhenwen, Xu Haihan, Chen Ziyuan. STUDIES ON THERMODYNAMIC PARAMETERS OF COORDINATION REACTIONS IN MOLYBDENUM(Ⅵ)-L-ASPARAGINE AND MOLYBDENUM (Ⅵ)-L-ASPARTIC ACID SYSTEMS[J]. Acta Physico-Chimica Sinica, ;1987, 3(03): 265-271. doi: 10.3866/PKU.WHXB19870309 shu

STUDIES ON THERMODYNAMIC PARAMETERS OF COORDINATION REACTIONS IN MOLYBDENUM(Ⅵ)-L-ASPARAGINE AND MOLYBDENUM (Ⅵ)-L-ASPARTIC ACID SYSTEMS

1.
Department of Chemistry; Shanghai Normal University

Received Date: 27 January 1986
Available Online: 15 June 1987

The maximum coordination number of complex of molybdenum (Ⅵ) with L- Asparagine has been determined by polarimetry. The complexes with 1:1 form in the systems of Molybdenum (Ⅵ)-L-Asparagine and Molybdenum(Ⅵ)-L- Aspartic acid were demonstrated by pH potentiometric studies. The thermodynmic parameters ΔHø、ΔGø、ΔS~ø of these coordination reactions have been reported and discussed in this paper.
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